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A number of historical people were named Alexander I:
- Alexander I of Macedon, king of Macedon 495-450 BC
- Alexander I of Epirus King of Epirus about 342 B.C.
- Pope Alexander I, Pope from 106 to 115
- Alexander I of Scotland (c. 1078-1124), King of Scotland
- Alexandru I cel Bun (Alexander the Good) (?-1432) a Voivode of Moldavia
- Alexander I of Georgia (1412-1442), King of Georgia
- Alexander I of Russia (1801-1825), Emperor of Russia
- Alexander I of Bulgaria (1857-1893), Prince of Bulgaria
- Alexander I of Greece (1917-1920), King of Greece
- Alexander I of Yugoslavia (1929-1934), King of Yugoslavia
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See also: Special:PrefixIndex/Alexander I and All pages with titles containing "Alexander I"