File:Ciba Foundation Symposium on the Regulation of Cell Metabolism (1959) (20610982605).jpg

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Title: Ciba Foundation Symposium on the Regulation of Cell Metabolism
Identifier: cibafoundationsy1959ciba (find matches)
Year: 1959 (1950s)
Authors: Ciba Foundation Symposium on the Regulation of Cell Metabolism (1958 : London, England); Wolstenholme, G. E. W. (Gordon Ethelbert Ward); O'Connor, Cecilia M. (Cecilia Mary), 1927-
Subjects: Cell metabolism
Publisher: Boston, Little, Brown
Contributing Library: MBLWHOI Library
Digitizing Sponsor: MBLWHOI Library

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156 F. Dickens, G. E. Clock and P. McLean phosphate pathway. At this stage, G6P can undergo a two- stage TPN-Unked oxidation, the first oxidation yielding 6-phosphogluconolactone (Cori and Lipmann, 1952): G6P2- + TPN+ -> 6-PG lactone^- + TPNH + H+ whilst the slow hydrolysis of this lactone is then accelerated by a widely distributed but little studied lactonase (see I GLYCOGEN I <-^fGTPl ATP GLUCOSE ^^ H ME ^^^, TPN -1 ^TPNH ATPx ;F6Pk ^I6PGLACT0NE; -4i \(AG;, XH^O -5
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IDP J' "' 'vT^'v RECYCLING ^^ / \6\ (AG'ca.O) \l?^(iO/—^ \?'^I? -^^ ^^)^ OAA^C; iC02j^ ylPYRUVATEl^^lLACTATEl DPNiK L^TPNH / 1?H ICITRATE.etcl ^^^IMALATEI —fv^ iFUMARATE.etcl Fig. 2. Approximate free-energy changes involved in glycolysis and the hexose monophosphate oxidative pathways. Values of AG' represent free energy changes at pH 7 and are rounded to nearest 0-5 kg. cal./mole (Krebs and Romberg, 1957; see also text). "Citrate, etc" and "Fumarate, etc" indicate points of linking with Krebs cycle reactions. Fig. 2); the same enzyme appears to hydrolyse S-glucono- lactone QLipmann and Brodie, 1955): 6-PG lactone^- + H2O -> G-PG^- + H+. It is unfortunate that accurate free energy values for these reactions are not available. The similar reaction with partially

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