File:Anti-aldol formation via E enolate.svg
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Summary[edit]
| Description |
English: Anti-aldol formation via E-enolate. A ketone 1 reacts with chlorodicyclohexylborane (Cy2BCl), in presence of triethylamine (TEA) in diethyl ether as solvent, leading to an E-enolate 2 (yield about 99%). Addition of an aldehyde results in an antiperiplanar aldol addition adduct 3 (yield: 95%).
Español: Formación del aldol anti por medio del enolato E. Una cetona 1 reacciona con diciclohexilcloroborano (Cy2BCl), en presencia de trietilamina (TEA) en éter dietílico como solvente, conduciendo a un E-enolato 2 (rendimiento aproximado del 99%). La adición de un aldehído lleva a un aducto de adición aldólica antiperiplanar 3 (rendimiento: 95%). |
| Date | |
| Source | Own work |
| Author | Omegakent |
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| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 12:30, 13 September 2010 | | 409 × 60 (12 KB) | Omegakent (talk | contribs) | {{Information |Description={{en|1=''Anti''-aldol formation via ''E''-enolate.}} {{es|1=Formación del aldol ''anti'' por medio del enolato ''E''.}} |Source={{own}} |Author=Omegakent |Date=2010-09-13 |Permission= |other_versions= }} [[C |
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