File:Titanium(IV)-fluoride-from-xtal-column-3D-bs-17.png

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Ball-and-stick model of the column structure as part of the crystal structure of titanium tetrafluoride, TiF4.

The crystal structure consists of three, crystallographically different Ti4+ cations which are surrounded octahedrally by six F– ions each. Each TiF6 octahedron is connected to two other TiF6 octahedra equatorially, creating a ring with the composition Ti3F15. By connecting these rings axially with other rings, isolated columns are formed.

Structure determined by single-crystal X-ray diffraction reported in Z. Anorg. Allg. Chem. 1995, 621, 1227–1231 and is available as CSD entry 1639008 and ICSD entry 78737.

CAS® Registry Number: 7783-63-3

Colour code:

  Titanium, Ti: light grey
  Fluorine, F: light green
Model manipulated and image generated in CCDC Mercury 2022.3.0.
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Author Simon Weber
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current19:28, 21 April 2023Thumbnail for version as of 19:28, 21 April 2023859 × 1,957 (132 KB)Chem Sim 2001 (talk | contribs)== {{int:filedesc}} == {{Information | Description = Ball-and-stick model of the column structure as part of the crystal structure of titanium tetrafluoride, TiF<sub>4</sub>. The crystal structure consists of three, crystallographically different Ti<sup>4+</sup> cations which are surrounded octahedrally by six F<sup>–</sup> ions each. Each TiF<sub>6</sub> octahedron is connected to two other TiF<sub>6</sub> octahedra equat...

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